What Is the Chemical Composition of Lake Malawi Water?

What Is the Chemical Composition of Lake Malawi Water? How Does it Compare with Lakes Victoria and Tanganyika?

T he classic paper by Talling & Talling (1965), source of the table below, reviews the chemical composition of African lake waters, compiling both previously published and many original observations. In addition to providing a detailed table with reference values for some 67 lakes, the Tallings classify the lakes into three "conveniently, though arbitrarily, distinguished" classes according to their total ionic concentrations and electrical conductivity. Conductivity, measured in microsiemens (µS), or millionths of a siemens [formerly called micromhos (µmho)], is a sensitive index of total ionic concentration. Crudely and somewhat imprecisely stated, the higher the conductivity, the more total ions — the "harder" the water.

Class I lakes have low total concentrations of ions [alkalinity usually less than 6 milliequivalents per liter (meq/L); this term has fallen out of use], and conductivity of less than 600 µS (µmho). These lakes get their water from direct surface runoff or rivers with little salt. Class I includes Lakes Malawi, Malombe, Victoria, Tana, and George, among others.

Class II lakes have higher total ion concentrations (alkalinity of about 6 to 60 meq/L), and conductivity of between 600 and 6000 µS. The higher ion concentrations arise from "accumulation and evaporation in closed basins or by inflows rich in solutes and particularly sodium carbonate and bicarbonate" (p. 435), especially drainage from alkaline lavas. Lakes Tanganyika, Kivu, Edward, Albert, Turkana (Rudolf), Rukwa, and others are in this class.

Class III includes the saline lakes, with alkalinity usually greater than 60 meq/L and conductivity of 6000-160,000 µS. These lakes, which often contain solid mineral deposits such as trona, include Nakuru, Magadi, Natron, Manyara, Eyasi, Katwe, and others.

The table below is extracted from Talling & Talling (1965). It gives all the ranges of values tabulated for surface waters of Lake Malawi, with those of Lakes Victoria and Tanganyika for comparison. (Not repeated here are readings from 300 and 600 meters depth in L. Malawi, far below the level where there is enough dissolved oxygen for fishes to occur. Also omitted here are deep readings from Victoria and Tanganyika. One value that the Tallings cited, but considered doubtful, is included in brackets.) Notice that the values of most constituents in L. Malawi water are intermediate between those of the other lakes, and generally closer to those of L. Victoria. (Note: Aquarists who want to know how to add salts to their water to make it more like that of Lake Malawi may be interested in George Reclos's article at Malawi Cichlid Homepage, Make your Own Salt Mixtures. A nice discussion of the chemical information below is contained in an article by Carli Flenniken, also at Malawi Cichlid Homepage.)

Water Chemistry of the African Great Lakes

Chemical ConstituentL. VictoriaL. MalawiL. Tanganyika
Electrical conductivity
(µS = µmho)
91-145210-220606-620
Total solids
(mg/L)
76-118460
Sum of cations
(meq/L)
1.04-1.212.457.30-7.46
Sum of anions
(meq/L)
1.08-1.772.5-2.597.25-7.71
pH
8.0-8.88.5-8.68.66-9.06*
Na (sodium)
(mg/L)
10.4-13.521.057-63.6
K (potassium)
(mg/L)
3.7-4.26.418.0-35.5
Ca (calcium)
(mg/L)
5-1516.4-19.89.2-17.6
Mg (magnesium)
(mg/L)
1.59-84.7-8.839.2-43.3
HCO3 + CO3 (bicarbonate,
carbonate) (meq/L)
0.25-1.532.36-2.586.02-6.81
Cl (chloride)
(mg/L)
3.9-7.03.57-4.320.9-36.6
SO4 (sulfate) (mg/L)
(using ion-exchange resins)
2.35.57.2-15.3
SiO2 (dissolved silica)
(mg/L)
3-201.1-40.3-6.6
NO3 · N (nitrate-nitrogen)
(µg/L)
11-29below detection
limit
PO4 · P (phosphate)
(µg/L)
3-13<7-307
Total P (phosphorus)
(µg/L)
47-67[21 (doubtful)]

*No pH values for L. Tanganyika were available to Talling & Talling (1965). The values tabulated here were very kindly provided by Eric Coenen of Lake Tanganyika Fisheries Research, extracted from Technical Document TD/46 written by Plisnier et al. (1996) of LTR (Research for the Management of the Fisheries of Lake Tanganyika). These pH values for L. Tanganyika were measured on pelagic waters (near-surface and at various depths) every 1-2 weeks for 1 year using the same pH meter and standardized sampling methods. In more detail, the measurements at the surface and 100 m are as follows:

Lake Tanganyika: pH Measurements, 8/93-7/94

Depth and
Sampling Station
Mean ± SD Median No. of Samples
Surface      
Bujumbura (north end) 9.01 ± 0.239.03 29
Kigoma (east coast) 9.06 ± 0.139.06 30
Mpulungu (south end) 9.02 ± 0.159.02 32
100 meters      
Bujumbura (north end) 8.66 ± 0.218.68 30
Kigoma (east coast) 8.79 ± 0.138.77 29
Mpulungu (south end) 8.86 ± 0.128.90 31



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Last Update: 12 February 2005
Web Author: M. K. Oliver, Ph.D.
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